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I can't see any reason why having your processors fight each other (duel) would be much help :-)
Then again, if you mean dual processors, that will make a very large difference in user interaction. I used to have a dual Celeron 466MHz (the ABit BP6 motherboard, ah, good times...) and it always felt more responsive than even the 2GHz single processor machine sitting on my desk right now. Of course, the individual processors were much slower, but when one was busy crunching numbers, the other could keep X humming along nicely.
Of course, when you have one processor and you're running something that's going to take a lot of CPU time (like compression), you can run it with "nice -+19 {program}", which will make it run with the lowest possible priority. It might take a little longer to run, but it won't impact the responsiveness of your desktop as badly.
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